Multicoordinated metal complexes for use in metathesis...

C - Chemistry – Metallurgy – 07 – F

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C07F 15/00 (2006.01) B01J 23/46 (2006.01) C08G 61/06 (2006.01) C08G 61/08 (2006.01)

Patent

CA 2620019

Improved catalysts useful in alkyne or olefin metathesis are made by bringing into contact a multi-coordinated metal complex comprising a multidentate Schiff base ligand, and one or more other ligands, with a selected activating compound under conditions such that at least partial cleavage of a bond between the metal and the multidentate Schiff base ligand of said metal complex occurs.

Cette invention concerne des catalyseurs améliorés utilisés dans la métathèse alcynes ou d'oléfines, lesquels catalyseurs sont réalisés par mise en contact d'un complexe métallique à coordonnées multiples comprenant un ligand multidenté présentant une base de Schiff, et un ou plusieurs autres ligands, avec un composé activateur choisi dans des conditions permettant le déclenchement d'au moins un clivage partiel d'une liaison entre le métal et le ligand multidenté du complexe métallique.

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