Multidentate phosphite ligands, catalytic compositions...

C - Chemistry – Metallurgy – 07 – F

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C07F 9/145 (2006.01) C07C 253/10 (2006.01) C07C 255/04 (2006.01)

Patent

CA 2382166

Hydrocyanation reactions employing multidentate phosphite ligands and multidentate phosphite ligands are disclosed. The ligands have phenyl containing substituents attached to the ortho position of the terminal phenol group and/or attached to the ortho position of the bridging group. Catalyst compositions having such ligands achieve 97 % or greater distribution in hydrocyanation.

L'invention concerne des réactions d'hydrocyanation utilisant des ligands de phosphite polydentés, et les ligands de phosphite polydentés eux-mêmes. Ces ligands comportent des substituants phénylés reliés en position ortho du groupe phénol terminal et/ou reliés en position ortho du groupe de pontage. Les compositions catalytiques renfermant ces ligands permettent d'obtenir, par l'hydrocyanation, une distribution supérieure ou égale à 97 %.

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