Multinuclear complex and condensation product thereof

Details Multinuclear complex and condensation product thereof Multinuclear complex and condensation product thereof

C - Chemistry, Metallurgy

07

F

C07F 7/18 (2006.01) B01J 31/22 (2006.01) C07F 19/00 (2006.01) C07C 53/10 (2006.01) C07C 309/04 (2006.01) C07F 1/08 (2006.01) C07F 13/00 (2006.01) C07F 15/02 (2006.01) C07F 15/04 (2006.01) C07F 15/06 (2006.01) C08G 77/58 (2006.01)

Patent

CA 2641573

Disclosed is a multinuclear complex which has multiple metal atoms and a ligand (L) which satisfies the requirements (i), (ii), (iii) and (iv) and coordinates to the metal atoms: (i) the ligand (L) has a univalent group represented by the general formula (1) and/or a bivalent group represented by the general formula (2); (ii) the ligand (L) has five or more coordinating atoms each of which can coordinate to the metal atoms; and (iii) at least one of the coordinating atoms coordinates to two of the metal atoms, or, in two coordinating atoms which are randomly selected from the coordinating atoms, the minimum number of covalent bonds formed between these coordinating atoms is 1 to 5; and (iv) the ligand (L) is soluble in a solvent.

L'invention concerne un complexe polynucléaire comportant de multiples atomes de métal et un ligand (L) qui satisfait aux exigences (i), (ii), (iii) et (iv) et coordonne les atomes de métal : (i) le ligand (L) comporte un groupe univalent représenté par la formule générale (1) et/ou un groupe divalent représenté par la formule générale (2) ; (ii) le ligand (L) comporte cinq atomes de coordination ou plus pouvant chacun coordonner les atomes de métal ; (iii) au moins l'un des atomes de coordination coordonne deux des atomes de métal ou, pour deux atomes de coordination qui sont sélectionnés au hasard parmi les atomes de coordination, le nombre minimal de liaisons covalentes formées entre ces atomes de coordination est de 1 à 5 ; et (iv) le ligand (L) est soluble dans un solvant.

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