Multistage process for the preparation of oxo aldehydes...

C - Chemistry – Metallurgy – 07 – C

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C07C 47/02 (2006.01) C07C 29/16 (2006.01) C07C 45/50 (2006.01)

Patent

CA 2353061

The invention relates to a process for the multistage cobalt- or rhodium-catalyzed hydroformylation of olefins having 6 to 24 carbon atoms to give alcohols and/or aldehydes, where the olefins a) are hydroformylated in a hydroformylation step to a conversion of from 20 to 98%, b) the catalyst is removed from the resulting liquid reactor discharge, c) the resulting liquid hydroformylation mixture is separated into a low-boiler fraction comprising olefins and paraffins, and a bottoms fraction comprising aldehydes and/or alcohols, d) the olefins present in the low-boiler fraction are reacted in further process stages comprising the process steps a, b and c and the bottoms fractions of process steps c) of all process stages are combined.

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