N-(benzenesulfonyl) carbamates-herbicidal antidotes

C - Chemistry – Metallurgy – 07 – F

Patent

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Details

260/452, 71/8.1,

C07F 9/38 (2006.01) C07D 319/06 (2006.01)

Patent

CA 1097649

Abstract of the Disclosure N-(substituted benzenesulfonyl) carba- mates as new compositions of matter useful as active herbicidal antidotes to protect against and decrease crop injury when used with a thio- carbamate herbicide when applied in various methods; improved hervicidal compositions and utility of said compositions to protect against and decrease phytotoxic crop injury when employ- ing thiocarbamate herbicides and a two-part herbicide system comprising a first-part of one or more thiocarbamate herbicide and a second part of an effective antidote therefor compound said antidote compounds of the class N-benzene sulfonyl carbamates having the formula Image wherein X is hydrogen, bromo, chloro, methoxy, trifluoromethyl, and methyl; n is an integer from 1 to 3 inclusive, provided that when X is bromo, trifluoromethyl, or methoxy, n is 1; and R is selected from alkyl, haloalkyl wherein halo is chloro or fluoro, alkenyl, haloalkenyl and wherein halo is chloro, alkynyl, trifluoroacetamidomethyl, dialkylamino cyanoalkylthioalkyl, phosphonomethyl, lower alkyl substituted phenyl, 4-chlorophenylthiomethyl, alkoxyalkyl, alkythioalkyl, cyanoalkyl, alkoxy- carbonylalkyl, formamidoalkyl, alkoxycarbonylalkenyl, alkylcarbonylalkyl, 1,3-dioxacyclohexane-5,5-methy- lene, phenyl, chlorophenyl, benzyl, 4-chlorobenzyl, 4-methoxybenzyl, 3-pyridylmethyl, phenoxyethyl, 3-phenylpropyn-2-yl, methylthioacetimino, acetone imino and benzaldimino

262510

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