Nanocrystalline alloys of the fe3al(ru) type and use thereof...

C - Chemistry – Metallurgy – 30 – B

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C30B 29/52 (2006.01) C23C 24/00 (2006.01) C25B 1/26 (2006.01) C25B 11/08 (2006.01) C25B 11/10 (2006.01) C30B 28/02 (2006.01) C30B 31/02 (2006.01)

Patent

CA 2687129

The invention relates to a nanocrystalline alloy of the formula Fe3-X Al1+X My Tz in which: M is at least one catalytic species selected from the group comprising Ru, Ir, Pd, Pt, Rh, Os, Re, Ag and Ni; T is at least one member selected from the group comprising Mo, Co, Cr, V, Cu, Zn, Nb, W, Zr, Y, Mn, Cb, Si, B, C, O, N, P, F, S, Cl and Na; x is a number higher than -1 and no higher than +1; y is a number higher than 0 and no higher than +1; z is a number between 0 and +1. The invention also relates to the use of the above alloy in a nanocrystalline form or not for making electrodes intended in particular for the synthesis of sodium chlorate.

L'invention vise un alliage nanocristallin de formule : Fe3-X Al1+X My Tz; dans laquelle : M représente au moins une espèce catalytique choisi dans le groupe constitué par Ru, Ir, Pd, Pt, Rh, Os, Re, Ag et Ni; T représente au moins un élément choisi dans le groupe constitué par Mo, Co, Cr, V, Cu, Zn, Nb, W, Zr, Y, Mn, Cb, Si, B, C, O, N, P, F, S, Cl et Na; x est un nombre supérieur à -1 et inférieur ou égal à +1; y est un nombre supérieur à O et inférieur ou égal à +1; z est un nombre compris entre O et +1. L'invention vise aussi l'usage de l'alliage ci-dessus sous forme nanocristalline ou non pour la fabrication d'électrodes destinées notamment à la synthèse du chlorate de sodium.

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