Near-neutral chlorine dioxide bleaching of pulp

D - Textiles – Paper – 21 – C

Patent

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D21C 9/14 (2006.01) D21H 21/30 (2006.01) D21H 21/32 (2006.01)

Patent

CA 2643093

Final chlorine dioxide bleaching of lignocellulosic materials is most effective at a near-neutral pH but present industrial practice typically targets a final pH of between 3.5 and 4.0 because of the difficulty in achieving and maintaining near-neutral pH cost effectively. The in situ formation of bicarbonate before the addition of chlorine dioxide provides a way of maintaining the required near-neutral pH. Near-neutral final chlorine dioxide bleaching also produces a bleached pulp that is in a state that responds more effectively to fluorescent whitening or optical brightening agents.

La décoloration par dioxyde de chlore final de matériaux lignocellulosiques est plus efficace à un pH presque neutre mais la pratique industrielle actuelle cible un pH final compris entre 3,5 et 4,0 compte tenu de la difficulté à atteindre et maintenir un pH presque neutre de manière rentable. La formation in situ de bicarbonate avant l'addition de dioxyde de chlore constitue un moyen permettant de maintenir le pH presque neutre requis. La décoloration par dioxyde de chlore final presque neutre produit également une pulpe décolorée réagissant de manière plus efficace aux agents d'éclaircissement optiques ou aux agents de blanchissement fluorescents.

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