New anionic and neutral complexes of ruthenium (ii) with...

C - Chemistry – Metallurgy – 07 – F

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C07F 15/00 (2006.01)

Patent

CA 2441698

A class of anionic and neutral complexes of ruthenium (II) containing nitrogen oxide (NO) and optionally a nitrogen ligand is described; a process for their preparation is also described. The preparation process includes the use of starting complexes of ruthenium (III) which are reacted with suitable reagents so as to obtain complexes containing NO coordinated to ruthenium (II). Additional substitution reactions allow the introduction of new groups that coordinate to the ruthenium atom, among which some nitrogen ligands.

La présente invention concerne une classe de complexes anioniques et neutres de ruthénium (II) contenant de l'oxyde d'azote (NO) et éventuellement un ligand d'azote; ainsi qu'un procédé permettant leur préparation. Ledit procédé de préparation consiste à utiliser des complexes de départ de ruthénium (III) que l'on fait réagir avec des réactifs adaptés de manière à obtenir des complexes contenant du NO liés au ruthénium (II). Des réactions de substitution supplémentaires permettent l'introduction de nouveaux groupes qui se lient à l'atome de ruthénium, parmi lesquels figurent quelques ligands d'azote.

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