New bis-platinum complexes with polymethylene derivatives as...

C - Chemistry – Metallurgy – 07 – F

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C07F 15/00 (2006.01) A61K 31/28 (2006.01) C07C 231/02 (2006.01) C07C 231/12 (2006.01) C07C 231/14 (2006.01) C07C 233/56 (2006.01) C07C 237/10 (2006.01) C07C 273/18 (2006.01) C07C 275/14 (2006.01) C07C 277/08 (2006.01) C07C 279/12 (2006.01) C07C 303/34 (2006.01) C07C 307/06 (2006.01) C07C 279/24 (2006.01)

Patent

CA 2234638

Bis-platinum(II) complexes with polymethylene derivatives, the method of making the complexes, and the use of these complexes for the treatment of tumors in mammals, are disclosed. The bis- platinum(II) Complexes are of formula (I): Image wherein: X, Y, and Z ligands are selected from the group consisting of ammonia, chloride, bromide, iodide or carboxylate of formula R-COO-C1-C4, in which R is a (C1-C4)alkyl group, with the proviso that two of X, Y, and Z are ammonia, the other being selected among chloride, bromide, iodide, and carboxylate R-COO-; n and m, which can be the same or different, are an integer from 2 to 8; p is the integer 1 or 2; the bifunctional ligand A is a polymethylene derivative; Q- p is a suitable counter- ion, comprising enantiomers and diastereoisomers thereof. The method of making the polymethylene derivatives, is also disclosed.

Cette invention se rapporte à des complexes de bis-platine (II) comportant des dérivés de polyméthylène, à un procédé de fabrication de ces complexes et à l'utilisation de ces complexes pour traiter des tumeurs chez les mammifères. L'invention se rapporte également au procédé de fabrication des dérivés de polyméthylène.

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