New fluorine-containing compounds having polyacetalic...

C - Chemistry – Metallurgy – 07 – C

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C07C 43/315 (2006.01) C08G 2/38 (2006.01) C08G 4/00 (2006.01) C08G 16/02 (2006.01) C08G 65/00 (2006.01) C08G 65/324 (2006.01) C08G 65/329 (2006.01) C08G 65/331 (2006.01)

Patent

CA 2095742

NEW FLUORINE-CONTAINING COMPOUNDS HAVING POLYACETALIC STRUCTURE, AND PROCESS FOR PREPARING THEM ABSTRACT 1) New fluorine-containing compounds having polyacetalic structure, of general formula: (I) Image where: Rf = a perfluorooxyalkylene chain having ?n from 500 to 5,000; m = 4 - 25; c = 1 - 10; n = 2 - 100. 2) A process for preparing them, which comprises carrying out the polycondens- ation of diols having formula: (II) HORfOH with formaldehyde, in mass or in the presence of solvents, in an acid medium. The compounds of formula (I) can be oligomeric compounds (polymerization degree ?nfrom 2 to about 20) or polymeric compounds (?nfrom about 20 to about 100). They exhibit a high stability to heat and to chemical agents, and Tg values slight ly different from the ones of the diols utilized for preparing them.

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