Nitration of organic compounds

C - Chemistry – Metallurgy – 07 – C

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260/463.7, 260/6

C07C 201/04 (2006.01) C07C 201/02 (2006.01) C07C 201/08 (2006.01) C07C 203/00 (2006.01) C07C 203/02 (2006.01) C07C 205/02 (2006.01)

Patent

CA 1212954

ABSTRACT Nitration of organic compounds. Organic nitrogen compounds are formed in the vapour phase by organic radical formation by reaction of an organic compound, suitably an alkane, with hydroxyl radicals derived from the reaction between hydrogen peroxide and nitrogen dioxide and the nitration of the organic radicals, suitably with nitrogen dioxide. The process is conducted using a molecular oxygen additive which directs the reaction towards the formation of the nitrate corresponding to the organic compound which may predominate in the organic reaction products.

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