Nitration of pyridine-2,6-diamines

C - Chemistry – Metallurgy – 07 – D

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C07D 213/73 (2006.01) C07D 213/74 (2006.01)

Patent

CA 2232463

It has been found that the nitration of pyridine-2,6-diamines, which is commonly performed in a mixture of nitric acid and concentrated sulphuric acid, will give a significantly higher yield (from about 50 % up to more than 90 %) if the reaction is carried out in a mixture of nitric acid and oleum, or by otherwise providing an inherently anhydrous medium.

On a trouvé que la nitrification de pyridine-2,6-diamines, lorsqu'on la réalise de manière classique dans un mélange d'acide nitrique et d'acide sulfurique concentré, donne un rendement nettement supérieur (d'environ 50 % à plus de 90%) si l'on effectue la réaction dans un mélange d'acide nitrique et d'oléum, ou bien si on l'effectue dans un milieu intrinsèquement anhydre.

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