Nitric oxide microsensors via fluorosilane-based xerogel...

C - Chemistry – Metallurgy – 08 – L

Patent

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Details

C08L 83/08 (2006.01) G01N 27/40 (2006.01) G01N 27/404 (2006.01) G01N 33/84 (2006.01) G01N 27/28 (2006.01) G01N 27/30 (2006.01)

Patent

CA 2661005

The presently disclosed subject matter relates to sensors for measuring an amount of a gaseous species in a sample. The sensors comprise a gas permeable polysiloxane network membrane, comprising both alkyl and fluorinated alkyl groups. In some embodiments, the polysiloxane network can be formed from the co-condensation of a mixture of an alkylalkoxysilane and a fluorosilane. The presently disclosed subject matter also relates to methods of making the sensors, methods of selectively measuring an amount of a gaseous species, such as nitric oxide, in a sample, and to compositions comprising the polysiloxane networks.

L'invention concerne des capteurs destinés à mesurer une quantité d'une espèce gazeuse dans un échantillon. Les capteurs comportent une membrane à réseau polysiloxane perméable au gaz incluant à la fois des groupes alkyle et des groupes alkyle fluoré. Dans certains modes de réalisation, le réseau polysiloxane peut être formé à partir de la co-condensation d'un mélange d'un alkylalcoxysilane et d'un fluorosilane. La présente invention concerne également des procédés de fabrication de capteurs, des procédés de mesure sélective d'une quantité d'une espèce gazeuse comme de l'oxyde nitrique dans un échantillon et des compositions incluant les réseaux polysiloxane.

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