Non-crystalline mesomorphous polypropylene articles with...

B - Operations – Transporting – 29 – C

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204/91.72

B29C 71/04 (2006.01) C08J 7/18 (2006.01) D04H 1/56 (2006.01)

Patent

CA 1299515

Abstract POLYPROPYLENE ARTICLES AND METHOD FOR PREPARING SAME Polypropylene articles are provided. The polypropylene articles comprise non-crystalline mesomorphous polypropylene hav- ing olefinic unsaturation-containing monomers graft-polymerized thereon by ionizing radiation in a dosage sufficient to degrade crystalline polypropylene. The irradiated polypropylene articles retain useful tensile properties after storage periods of as long as at least about four months. Further provided is a method for preparing irradiated polypropylene articles having olefinic unsaturation-containing monomers graft-polymerized thereon comprising the steps of melt extruding polypropylene; quenching the extruded polypropylene immediately after extrusion to provide non-crystalline mesomorphous polypropylene; coating the non- crystalline mesomorphous polypropylene with an ionizing radiation graft-polymerizable monomer; and irradiating the coated non- crystalline mesomorphous polypropylene with a dosage of ionizing radiation sufficient to degrade crystalline polypropylene and sufficient to effect graft-polymerization of the monomer onto the surface of the polypropylene.

568393

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