Non-oxidative dehydrogenation process

C - Chemistry – Metallurgy – 07 – C

Patent

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260/675.2

C07C 5/42 (2006.01) B01J 23/86 (2006.01) C07C 5/333 (2006.01)

Patent

CA 1072987

K 5909 A B S T R A C T The invention relates to a process for the preparation of a compound having the formula R-CH=CH2 by non-oxidative dehydrogenation of a compound having the formula R-CH2-CH3, wherein R is a phenyl, alkyl or alkenyl group. This process comprises passing a mixture of a compound having the formula R-CH2-CH3 , wherein R is a phenyl, alkyl or alkenyl group, and superheated steam at the dehydrogenation temperature, over a catalyst which is a spinel with an alkaline metal as accelerator. Application in the manufacture of styrene.

262968

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