Non-whitening emulsion pressure sensitive adhesives

C - Chemistry – Metallurgy – 09 – J

Patent

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Details

400/9071, 400/92

C09J 135/02 (2006.01) B32B 7/12 (2006.01) C08F 220/10 (2006.01) C08F 220/18 (2006.01) C08F 265/06 (2006.01)

Patent

CA 2317773

The invention provides a water-resistant emulsion pressure sensitive adhesive comprising a reaction product formed from a polymerizable mixture of (a) 50-90% by weight n-butyl acrylate, and (b) 10-50% by weight 2-hydroxy ethyl acrylate, 2-hydroxy ethyl methacrylate, or hydroxy propyl acrylate monomer; wherein the water-resistant emulsion pressure sensitive adhesive exhibits optical measurements of (i) less than 2% increase in haze, (ii) less than 20 increase in opacity, and (iii) greater than approximately 95% transmittance in the visible spectrum ranging from 370 to 720 nm after a wet lamination process in which a clear, primed polyester film coated with the water-resistant emulsion pressure sensitive adhesive is wet laminated to a glass slide, wherein the optical measurements are measured relative to control optical measurements of a dry laminate formed by a dry lamination process in which a clear, primed polyester film coated with the water-resistant emulsion pressure sensitive adhesive is dry laminated to a glass slide. The water-resistant, low haze acrylic-based (latex) pressure sensitive adhesives of the invention may be used in decorative, light management or optical articles.

Cette invention concerne des compositions d'adhésifs autocollants à base d'une émulsion acrylique résistant à l'eau et ne blanchissant pas dans l'eau, lesquelles compositions peuvent être utilisées dans des films de régulation d'énergie ainsi que dans des films optiques. Ces adhésifs autocollants à base d'émulsion comprennent de 10 à 50 % de (méth)acrylate d'hydroxyalkyle, de 50 à 90 % de (méth)acrylate d'alkyle et de 0 à 6 % d'un agent de réticulation diacrylate. Ces adhésifs autocollants à base d'émulsion peuvent être utilisés dans des procédés de stratification à l'eau et possèdent un voile inférieur à 2 %, une opacité inférieure à 2 % ainsi qu'un facteur de transmission supérieur à 95 % au cours du processus de stratification à l'état mouillé.

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