Novel aromatic piperazines derived from substituted...

C - Chemistry – Metallurgy – 07 – D

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C07D 295/20 (2006.01) A61K 31/495 (2006.01) A61K 31/55 (2006.01) C07D 211/16 (2006.01) C07D 211/18 (2006.01) C07D 211/46 (2006.01) C07D 211/70 (2006.01) C07D 233/02 (2006.01) C07D 243/08 (2006.01) C07D 295/26 (2006.01) C07D 401/12 (2006.01) C07D 405/12 (2006.01)

Patent

CA 2245718

Compounds of formula (I), wherein R¿1? is hydrogen or straight or branched C¿1-6? alkyl, Z¿2? is O, NH, CH¿2?O or CH¿2?NH, each of R¿2? and R¿3?, which are the same or different, is hydrogen or a group selected from straight or branched alkyl, alkoxy, thioether, nitrile, trifluoromethyl or halogen (F, Cl, Br, I), or, when they are adjacent, R¿2? and R¿3?, taken together, form a 5- or 6-membered ring in order to form, e.g., naphthyl, tetrahydronaphthyl, benzopyrane or benzodioxane, X-Y is NCH¿2?, CH-CH¿2?, C=CH, N or NCH¿2?CH¿2?, and Z¿1? is -(CH¿2?)¿n?, -(CH¿2?)¿n? CO-, -CO-, -CO(CH¿2?)¿n?-, -SO¿2?-, -SO¿2?(CH¿2?)¿n?-, -O(CH¿2?)¿n?-, -O(CH¿2?)¿n?CO-, -OCO-, -NH(CH¿2?)¿n?-, -NH(CH¿2?)¿n?CO-, -NHCO-, -NHCO(CH¿2?)¿n?-, -NH(CH¿2?)¿n?SO¿2?-, -NHSO¿2?-, -NHSO¿2?(CH¿2?)¿n?-, -CH=CHCO-, -CCCO- -(CH¿2?)¿n?SO¿2?-, -O(CH¿2?)¿n?SO¿2?-.

La présente invention concerne les composés de formule (I) dans laquelle: R1 représente un hydrogène ou un alkyle linéaire ou ramifié comprenant de 1 à 6 atomes de carbone, Z2 représente O, NH, CH2O ou CH2NH, R2 et R3 identiques ou différents représentent un hydrogène ou un groupe choisi parmi un alkyle linéaire ou ramifié, un alcoxy, thioéther, nitrile, trifluorométhyle ou halogène (F, Cl, Br, I), ou, R2 et R3, lorsqu'ils sont adjacents, pris ensemble, forment un cycle à 5 ou 6 chaînons de façon à constituer par exemple un naphtyle, un tétrahydronaphtyle, un benzopyrane ou un benzodioxane, X-Y représente NCH2, CH-CH2, C=CH, N ou NCH2CH2, Z1 représente -(CH2)n, -(CH2)n CO- , -CO-, -CO(CH2)n-, -SO2-, -SO2(CH2)n-, -O(CH2)n-, -O(CH2)nCO-, -OCO-, - NH(CH2)n-, -NH(CH2)nCO-, -NHCO-, -NHCO(CH2)n-, -NH(CH2)nSO2-, -NHSO2-, - NHSO2(CH2)n-, -CH=CHCO-, -CCCO- -(CH2)nSO2-, -O(CH2)nSO2-.

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