Novel crystal of monohydrate of heterocyclic bis(phosphonic...

C - Chemistry – Metallurgy – 07 – F

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C07F 9/547 (2006.01) A61K 31/675 (2006.01) C07F 9/6561 (2006.01)

Patent

CA 2137665

Crystal D or E of 1-hydroxy-2-(imidazo[1,2-a]pyridin- 3-yl)ethane-1,1-bis(phosphonic acid) monohydrate having specified lattice spacing and relative intensity in the powder X-ray diffraction spectrum obtained by using Cu-K.alpha. radiation and a dehydration peak temperature of 135 to 149°C or 160 to 170°C according to TG-DSC thermogravimetric analysis; and to a solid pharmaceutical preparation containing the same. The crystals are useful for producing a stable solid pharmaceutical preparation of the above compound which has an excellent drug efficacy for diseases wherein increased bone resorption participates, such as osteoporosis.

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