Novel disulfides and thiol compounds

Details Novel disulfides and thiol compounds Novel disulfides and thiol compounds

C - Chemistry, Metallurgy

07

K

C07K 5/06 (2006.01) A23L 1/30 (2006.01) A61K 31/00 (2006.01) A61K 31/16 (2006.01) A61K 31/195 (2006.01) A61K 31/215 (2006.01) A61K 31/275 (2006.01) A61K 31/66 (2006.01) A61K 31/675 (2006.01) A61K 45/06 (2006.01) C07K 5/00 (2006.01) C07K 5/08 (2006.01)

Patent

CA 2321961

The present invention is directed to novel disulfides and thiols that are of up to about eighteen amino acids. One example is a compound of the formula (1): A-B-C-S-S-D-E-F, wherein A and F are selected from the group consisting of hydrogen, an amino acid, a dipeptide, a tripeptide, a modified polypeptide up to three amino acids long, and a carbobenzoxy group, B and E are selected from the group consisting of an amino acid, a dipeptide, a tripeptide, and a modified polypeptide comprising up to and including three amino acids, C and D are selected from the group consisting of a modified polypeptide and a polypeptide comprising up to and including three amino acids, and S is the sulfur atom in the modified polypeptide and the polypeptide in C and D.

L'invention concerne de nouveaux bisulfures et thiols qui comprennent jusqu'à environ dix-huit acides aminés. C'est le cas notamment d'un composé représenté par la formule (I): A-B-C-S-S-D-E-F, dans laquelle A et F sont choisis dans un groupe constitué de l'hydrogène, d'un acide aminé, d'un dipeptide, d'un tripeptide, d'un polypeptide modifié pouvant contenir jusqu'à trois acides aminés, et d'un groupe carbobenzoxy; B et E sont choisis dans un groupe constitué de l'hydrogène, d'un acide aminé, d'un dipeptide, d'un tripeptide, d'un polypeptide modifié pouvant contenir jusqu'à trois acides aminés; C et D sont choisis dans le groupe constitué d'un polypeptide modifié et d'un polypeptide pouvant contenir jusqu'à trois acides aminés; et S représente l'atome de soufre dans le polypeptide modifié et le polypeptide dans C et D.

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