Novel silicone compounds having sterically hindered cyclic...

C - Chemistry – Metallurgy – 08 – G

Patent

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C08G 77/26 (2006.01) C08G 77/388 (2006.01) C08K 5/544 (2006.01) C08L 83/08 (2006.01) C08L 101/00 (2006.01)

Patent

CA 2207110

Straight, cyclic or branched polyorganosiloxanes having at least three siloxyl units per molecule, including at least one functional unit of formula (I), wherein R<1> is a C1-4 alkyl radical or phenyl, and X contains a secondary or tertiary cyclic amine function bound to the silicon via a Si-A-C bond, where A is a purely hydrocarbon residue with low carbon condensation. Said cyclic amine function may be a sterically hindered piperidinyl function bound to the silicon via a Si-A-C bond, where A is a methylene, dimethylene or trimethylene residue. The use of such polyorganosiloxanes in polymers, in particular for improving the light-stability thereof, is also disclosed.

La présente invention concerne des polyorganosiloxanes linéaire, cycliques ou ramifiés ayant par molécule au moins trois motifs siloxyles dont au moins un motif fonctionnel de formule (I), où R1 représente un radical alkyle en C1 à C4 ou phényle, X renferme une fonction amine cyclique secondaire ou tertiaire liée au silicium par une liaison Si-A-C où A est un reste purement hydrocarboné de faible condensation en carbone. Ladite fonction amine cyclique peut être une fonction pipéridinyle stériquement encombrée liée au silicium par une liaison Si-A-C où A est un reste méthylène, diméthylène ou triméthylène. La présente invention concerne également l'utilisation de pareils polyorganosiloxanes dans les polymères pour améliorer notamment leur photostabilisation.

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