Novel zirconium compound, catalyst and its use for...

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B01J 31/22 (2006.01) C08G 18/16 (2006.01) C08G 18/22 (2006.01)

Patent

CA 2613743

The invention comprises a catalyst compound of formula Zr(L)(A1 )(A2)(A3) where L represents a ketoamide ligand, A1, A2 & A3 may be the same or different and each represent a ligand derived from a compound selected from the group consisting of:- an alcohol, a polyol, an alkyl acetoacetate, a diketone, a ketoamide, a carboxylic acid or ester thereof, an alkanolamine, a phosphoric acid ester and a sulphonic acid or ester thereof. The compound may be made by the reaction of a zirconium alkoxide or haloalkoxide with a ketoamide. The compound is useful as a catalyst for the reaction of a polyisocyanate with a hydroxyl-containing compound, e.g. for the manufacture of polyurethanes or composite cellulosic materials such as fibre-boards.

L'invention concerne un composé catalytique de formule Zr(L)(A1)(A2)(A3) dans laquelle L représente un ligand cétoamide, A1, A2 et A3 peuvent être identiques ou différents, et chacun représente un ligand dérivé d'un composé choisi dans le groupe consistant en : - un alcool, un polyol, un acétoacétate d'alkyle, une dicétone, une cétoamide, un acide carboxylique ou un ester de cet acide, une alcanolamine, un ester d'acide phosphorique, et un acide sulfonique ou un ester de cet acide. Le composé peut être obtenu par réaction d'un halogénoalcoxyde ou d'un alcoxyde de zirconium avec un cétoamide. Le composé est utile en tant que catalyseur pour la réaction d'un polyisocyanate avec un composé contenant un hydroxyle, par exemple pour la fabrication de polyuréthannes ou de matériaux cellulosiques composites tels que des panneaux de fibres.

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