Nucleic acids internally-derivatized with a texaphyrin metal...

C - Chemistry – Metallurgy – 07 – H

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C07H 21/00 (2006.01) A61K 31/70 (2006.01) A61K 47/48 (2006.01) A61K 48/00 (2006.01) C12N 15/11 (2006.01) C12Q 1/68 (2006.01)

Patent

CA 2263137

Texaphyrin metal complex-oligonucleotide and -oligonucleotide analog conjugates are provided where the texaphyrin is bound to an internal linkage of the oligonucleotide or oligonucleotide analog, the conjugates having catalytic activity for the hydrolysis of ribonucleic acid. Further, conjugates demonstrating catalytic turnover are described, the conjugates being especially effective under conditions where the concentration of RNA target exceeds that of available conjugate.

La présente invention a pour objet des conjugués d'oligonucléotides et d'analogues d'oligonucléotides avec un complexe métallique de téxaphyrine, dans lesquels la téxaphyrine est liée à une liaison interne de l'oligonucléotide ou de l'analogue d'oligonucléotide, les conjugués ayant une activité catalytique servant à l'hydrolyse de l'acide ribonucléique. La présente invention a en outre pour objet des conjugués présentant un rendement catalytique, ces conjugués étant particulièrement efficaces dans des états dans lesquels la concentration de la cible ARN dépasse celle du conjugué disponible.

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