Obtaining but-2-enes from c.sub.4-hydrocarbon mixtures which...

C - Chemistry – Metallurgy – 07 – C

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260/709

C07C 5/25 (2006.01) C07C 7/04 (2006.01) C07C 11/08 (2006.01)

Patent

CA 1251473

Abstract of the Disclosure: But-2-enes are obtained from C4-hydrocarbon mixtures which contain but-1-ene and may or may not contain but-2-enes by catalytic isomerization of the but-1-ene to but-2-enes in an isomerization zone at elevated temperatures by a process in which the iso- merization is carried out in combination with a distillative separation zone, the said hydrocarbon mixture being fed to the isomerization zone and/or distillative separa- tion zone, the isomerization mixture obtained from the isomerization zone is passed into the distillative separa- tion zone, a but-1-ene-containing fraction is removed above the lower third of the distillative separation zone and passed into the isomerization zone, and the but-2-enes or a fraction containing these are or is removed in the lower third of the distillative separation zone.

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