Olefin oligomerization process and catalyst

Details Olefin oligomerization process and catalyst Olefin oligomerization process and catalyst

B - Operations, Transporting

01

J

B01J 31/06 (2006.01) B01J 31/12 (2006.01) B01J 31/26 (2006.01) C07C 2/20 (2006.01) C07C 2/30 (2006.01) C07C 2/34 (2006.01) C07C 11/02 (2006.01) C10G 50/02 (2006.01)

Patent

CA 2239182

Alpha-olefin oligomer is prepared by contacting an alpha-olefin monomer which contains from about 8 to about 20 carbon atoms with a heterogeneous catalyst system formed from (i) a solid olefin polymer having a linear backbone and a plurality of pendant omega-hydroxyalkyl groups, (ii) a boron trihalide, preferably BF3, and, optionally (iii) an organomagnesium halide.

On prépare un oligomère alpha-oléfinique en mettant en contact un monomère alpha-oléfinique renfermant entre environ 8 et environ 20 atomes de carbone avec un système catalyseur hétérogène obtenu à partir de: (i) un polymère oléfinique solide à squelette linéaire et à pluralité de groupes oméga-hydroxyalkyle labiles, (ii) un trihalogénure de bore, de préférence BF¿3?, et éventuellement (iii) un halogénure d'organomagnésium.

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