Olefin polymerization catalyst and process and polymer,...

C - Chemistry – Metallurgy – 08 – F

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Details

C08F 4/70 (2006.01) C08F 8/10 (2006.01) C08F 10/00 (2006.01) C08F 110/02 (2006.01) C08F 210/16 (2006.01) C10L 1/10 (2006.01) C10L 1/16 (2006.01) C10L 1/18 (2006.01) C10L 1/22 (2006.01) C10M 129/93 (2006.01) C10M 129/95 (2006.01) C10M 133/52 (2006.01)

Patent

CA 2409110

This invention is directed to a catalyst and an associated process for polymerizing olefins or olefin-containing compounds, to corresponding olefin polymers, to derivatives of the olefin polymers, and to lubricant and fuel compositions that include the olefin polymers or their derivatives. The polymerization catalyst is a metal complex and optional cocatalyst where the metal complex is formed from a bidentate ligand having a nitrogen coordinating group and a second coordinating group selected from oxygen, sulfur, selenium and tellurium groups and a metal compound where the metal is a transition metal, boron, aluminum, germanium or tin. Highly branched and reactive ethylene polymers are formed from the catalyst and process of the present invention. The ethylene polymers and their derivatives are useful in various applications including as performance additives in lubricants and fuels.

L'invention se rapporte à un catalyseur et à un procédé associé pour la polymérisation d'oléfines ou de composés contenant des oléfines, à des polymères oléfiniques correspondants, à des dérivés de polymères oléfiniques et à des compositions de lubrifiant et de carburant comprenant lesdits polymères oléfiniques ou leurs dérivés. Le catalyseur de polymérisation est un complexe métallique et éventuellement un cocatalyseur, le complexe métallique étant formé à partir d'un ligand bidenté possédant un groupe de coordination azote et un second groupe de coordination choisi parmi les groupes tellurium et sélénium, oxygène et soufre et un composé métallique dans lequel le métal est un métal de transition, du bore, de l'aluminium, du germanium ou de l'étain. On forme des polymères d'éthylène hautement ramifiés et réactifs à partir du catalyseur et du procédé de l'invention. Les polymères d'éthylène et leurs dérivés sont utiles dans diverses applications, par exemple en tant qu'additifs de performance dans les lubrifiants et les carburants.

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