Olefin skeletal isomerization process

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 1/00 (2006.01) C07C 2/66 (2006.01) C07C 4/14 (2006.01) C07C 5/22 (2006.01) C07C 11/02 (2006.01)

Patent

CA 2290606

An isomerization process for C4 to C15 olefins carried out by the reaction of C4 to C15 olefins, having a first skeletal distribution, with aromatic compounds under alkylation conditions to produce an alkylated aromatic product, dealkylation of the alkylated aromatic product under dealkylation conditions to produce a dealkylated product comprising said aromatic compounds and olefins corresponding to the olefins in the alkylation and having a second skeletal distribution different than said first skeletal distribution. Acidic catalysts such as molecular sieves are used in both alkylation and dealkylation. The reactions may be carried out in either straight pass fixed beds or in catalytic distillation reactors.

L'invention porte sur un procédé d'isomérisation d'oléfines C¿4? à C¿15? consistant à faire réagir lesdites oléfines présentant une première structure de squelette avec des composés aromatiques dans des conditions d'alkylation de manière à produire un produit aromatique alkylé, puis à desalkyler ledit produit dans des conditions de désalkylation de manière à produire un produit aromatique désalkylé comprenant lesdits composés aromatiques et les oléfines correspondantes et présentant une deuxième structure de squelette. Les catalyseurs acides tels que les cribles moléculaires peuvent servir à la fois pour l'alkylation et la désalkylation les réactions peuvent se dérouler soit dans des lits fixes à passage droit, soit dans des réacteurs catalytiques à distillation.

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