Olefin trimerisation using a catalyst comprising a source of...

B - Operations – Transporting – 01 – J

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B01J 31/18 (2006.01) B01J 31/24 (2006.01) B01J 31/34 (2006.01) C07C 2/36 (2006.01) C07C 11/107 (2006.01) C07F 9/46 (2006.01) C07F 9/50 (2006.01) C08F 10/00 (2006.01) C08F 10/02 (2006.01) B01J 23/26 (2006.01) C08F 4/659 (2006.01) C08F 4/6592 (2006.01)

Patent

CA 2412990

A process for the trimerisation of olefins is disclosed, comprising contacting a monomeric olefin or mixture of olefins under trimerisation conditions with a catalyst which comprises (a) a source of chromium, molybdenum or tungsten (b) a ligand containing at least one phosphorus, arsenic or antimony atom bound to at least one hydrocarbyl or heterohydrocarbyl group having a polar substituent, but excluding the case where all such polar substituents are phosphane, arsane or stibana groups; and optionally (c) an activator.

La présente invention concerne un procédé de trimérisation d'oléfines. Ce procédé consiste à mettre en contact une oléfine monomère ou un mélange d'oléfines, dans des conditions de trimérisation, avec un catalyseur qui comprend (a) une source de chrome, de molybdène ou de tungstène, (b) un ligand contenant au moins un atome de phosphore, d'arsenic ou d'antimoine, qui est lié à au moins un groupe hydrocarbyle ou hétérocarbyle présentant un substituant polaire, à l'exception du cas où tous lesdits substituants polaires sont des groupes phosphane, arsane ou stibane, ainsi qu'éventuellement (c) un activateur.

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