One package aqueous latices containing alkaline- curable...

C - Chemistry – Metallurgy – 08 – K

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400/1348, 400/13

C08K 5/09 (2006.01) C08J 3/03 (2006.01) C08K 5/098 (2006.01) C08L 31/04 (2006.01) C08L 33/06 (2006.01)

Patent

CA 1263491

ABSTRACT OF THE DISCLOSURE Shelf-stable, one-package aqueous latices, useful as adhesives, coatings or binders, which are curable with or without the application of heat, consist essentially of an alkaline-curable, self-crosslinking emulsion polymer, selected organic metal salts, and water. The alkali, alkaline earth, or heavy metal salts of C1-C6 organic acids (e.g., sodium acetate) are post-added to the polymer emulsion or present during the polymerization. The polymer typically comprises about 90-99.92 by weight of one or more vinyl polymerizable monomers (e.g., acrylates, vinyl esters, and ethylene and 0.1-10% by weight of a polymerizable non-ionic or cationic self-crosslinking monomer containing halohydrin groups (e.g., 3-chloro-2-hydroxypropyl (meth)acrylate or the reaction product of epichlorohydrin and N,N-dimethylaminopropyl methacrylamide or methacrylate).

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