One-pot process for the preparation of...

C - Chemistry – Metallurgy – 07 – D

Patent

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C07D 249/20 (2006.01)

Patent

CA 2359087

5-Sulfonyl substituted benzotriazole UV absorbers are prepared from the corresponding 5-chlorobenzotriazole in a two step, but one-pot process where the second step involves the oxidation of the non-isolated 5-thio substituted benzotriazole using sodium tungstate, hydrogen peroxide and formic acid. The 5- sulfonyl substituted benzotriazoles exhibit enhanced absorption in the near- visible range (over 350 nm) thus providing effective protection to substrates in this critical area of the spectrum.

Cette invention se rapporte à des filtres anti-UV au benzotriazole à substitution 5-sulfonyle, qui sont préparés à partir du 5-chlorobenzotriazole correspondant dans un procédé en deux étapes mais monotope, dans lequel la seconde étape consiste à oxyder le benzotriazole à substitution 5-thio non isolé à l'aide de tungstate de sodium, de peroxyde d'hydrogène et d'acide formique. Ces benzotriazoles à substitution 5-sulfonyle présentent une absorption accrue dans la gamme proche du visible (au-dessus de 350 nm), offrant ainsi une protection efficace au substrat dans cette région critique du spectre.

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