One-step production of 1,3-propanediol from ethylene oxide...

C - Chemistry – Metallurgy – 07 – F

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C07F 15/00 (2006.01) B01J 31/24 (2006.01) C07F 15/06 (2006.01)

Patent

CA 2449418

A catalyst composition comprising: (a) a cobalt component comprising one or more non-ligated cobalt compounds; and (b) a ruthenium component comprising in major part a ruthenium carbonyl compound ligated with a phospholanoalkane ligand; and a process for preparing 1,3-propanediol using such a catalyst composition.

L'invention concerne une composition catalytique comprenant: (a) un composant à base de cobalt contenant un ou plusieurs composés de cobalt sans ligand, et (b) un composant à base de ruthénium contenant en majeure partie un composé de ruthénium carbonyle comportant un ligand phospholanoalcane. L'invention concerne aussi un procédé de préparation de 1,3-propanediol à l'aide d'une telle composition catalytique.

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