One-step production of 1,3-propanediol from ethylene oxide...

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B01J 31/20 (2006.01) B01J 31/28 (2006.01) C07C 29/16 (2006.01) C07F 15/00 (2006.01) C07F 15/06 (2006.01)

Patent

CA 2447133

A catalyst composition comprising: a) a cobalt component comprising one or more non-ligated cobalt carbonyl compounds; and b) a ruthenium component comprising a ruthenium carbonyl compound ligated with a N-heterocyclic ligand selected from the group consisting of bidentate and multidentate N- heterocyclic ligands; and a process for preparing 1,3-propanediol using such a catalyst composition.

L'invention concerne une composition catalysante qui comprend: a) un constituant cobalt contenant un ou plusieurs composés cobalt-carbonyles non liés aux ligands; et b) un constituant ruthénium contenant un composé ruthénium-carbonyle lié avec un ligand N-hétérocyclique sélectionné dans le groupe constitué par des ligands N-hétérocycliques bidentés ou multicoordinants. L'invention concerne en outre une méthode de préparation de 1,3-propanediol mettant en oeuvre ladite composition catalysante.

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