One step synthesis of methyl t-butyl ether from t-butanol...

Details One step synthesis of methyl t-butyl ether from t-butanol... One step synthesis of methyl t-butyl ether from t-butanol...

C - Chemistry, Metallurgy

07

C

C07C 43/04 (2006.01) C07C 41/01 (2006.01) C07C 41/09 (2006.01)

Patent

CA 2069395

ONE STEP SYNTHESIS OF METHYL t-BUTYL ETHER FROM t-BUTANOL USING FLUOROCARBON SULFONIC ACID POLYMERS ON INERT SUPPORTS (D#80,970-F) ABSTRACT OF THE DISCLOSURE A method is disclosed wherein t-butanol is reacted with methanol in a reaction zone in one step to provide methyl tert-butyl ether and the improvement of accomplishing the reaction which comprises: a. Using a catalyst consisting of a fluorocarbon sulfonic acid polymer supported on an inert carrier; b. continuously contacting said t-butanol and methanol in a molar amount of about 0.1 to 10 moles of methanol per mole of t-butanol with said catalyst at a temperature of about 20°C to about 250°C and a pressure of about atmospheric to about 1000 psig to obtain the methyl tert-butyl ether product. CK\80970.app

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