Optical article comprising a multilayer anti-reflective...

G - Physics – 02 – B

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G02B 1/11 (2006.01) C08J 7/04 (2006.01) C09D 183/08 (2006.01)

Patent

CA 2534183

The invention relates to an optical article, for example, an ophthalmic lens, comprising at least one multilayer anti-reflective coating on a transparent substrate made from organic or mineral glass. Said coating comprises successively and starting at the substrate, a layer of material with high refractive index (HI), made from a hybrid organic/inorganic matrix within which are dispersed particles of mineral oxide or chalcogenide with a diameter of 2 to 50 nm and a layer of material with low refractive index (BI), obtained by hardening of a composition comprising at least one silane precursor (I) with 4 hydrolysable groups and at least one fluorosilane precursor (II), said second composition comprising at least 10 % in mass of fluorine in a theoretical dry extract and with a molar ratio I/I+II greater than 80 %.

La présente invention concerne un article d'optique, par exemple une lentille ophtalmique, comprenant au moins un empilement anti-reflets multicouches sur un substrat transparent en verre organique ou minéral, ledit empilement comprenant, successivement et dans l'ordre à partir du substrat, au moins une couche de matériau de haut indice de réfraction (HI) comprenant une matrice hybride organique-inorganique dans laquelle sont dispersées des particules d'oxyde minéral et/ou chalcogénure d'un diamètre de 2 à 50 nm, et une couche de matériau bas indice de réfraction (BI) obtenue par durcissement d'une composition comprenant au moins un silane précurseur (I) ayant 4 parties hydrolysables et au moins un fluorosilane précurseur (II), cette seconde composition comprenant au moins 10% en masse de fluor dans son extrait sec théorique et un rapport molaire I/I+II supérieur à 80%.

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