Optical article containing a linear condensation polymer...

C - Chemistry – Metallurgy – 08 – G

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402/320, 345/60

C08G 75/20 (2006.01) C08F 8/34 (2006.01) G02F 1/065 (2006.01) G02F 1/361 (2006.01) G02F 1/377 (2006.01)

Patent

CA 2002248

AN OPTICAL ARTICLE CONTAINING A LINEAR CONDENSATION POLYMER EXHIBITING A HIGH LEVEL OF SECOND ORDER POLARIZATION SUSCEPTIBILITY ABSTRACT OF THE DISCLOSURE An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10-9 electrostatic units comprised of a linear polymer containing polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor moiety to permit oscillation of the molecular dipole between a ground state exhibiting a first dipole moment and an excited state exhibiting a differing dipole moment. The linear polymer is a condensation polymer including in its backbone a plurality of molecular dipoles including sulfonyl electron acceptor moieties sequentially arranged to reinforce electron displacement along the polymer backbone.

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