Optical article containing a linear polymer exhibiting a...

G - Physics – 02 – F

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345/11, 402/12

G02F 1/35 (2006.01) C08F 20/36 (2006.01) G02F 1/37 (2006.01)

Patent

CA 1289295

AN OPTICAL ARTICLE CONTAINING A LINEAR POLYMER EXHIBITING A HIGH LEVEL OF SECOND ORDER POLARIZATION SUSCEPTIBILITY Abstract of the Disclosure An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10-9 electrostatic units comprised of a linear polymer containing as pendant groups polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor moiety to permit oscillation of the molecular dipole between a ground state exhibiting a first dipole moment and an excited state exhibiting a differing dipole moment. The linear polymer contains repeating units derived from vinyl addition polymerization, at least 5 percent of the repeating units incorporate the molecular dipoles as pendant groups, and the molecular dipoles include a sulfonyl electron acceptor moiety.

576543

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