Optically active 3,4-bis(diphenylphosphino) pyrrolidines,...

C - Chemistry – Metallurgy – 07 – F

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C07F 15/00 (2006.01) B01J 31/24 (2006.01) C07D 207/12 (2006.01) C07D 207/416 (2006.01) C07D 209/20 (2006.01) C07D 317/58 (2006.01) C07F 9/572 (2006.01)

Patent

CA 1238913

ABSTRACT OF THE DISCLOSURE Novel optically active 3,4-bis-(diphenylphosphino) pyrrolidines having the formula Image wherein Ph represents a phenyl radical and R represents hydrogen, an alkyl radical, an arylalkyl radical, or an acyl radical, and rhodium complexes containing them as chiral ligands as well as their use as catalysts for the homogeneous asymmetric hydrogenation of unsubstituted or .beta.-substituted .alpha.-acylamino-acrylic acids are described.

473217

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