Optically active ethers used for resolution of (r,s) -cyano...

C - Chemistry – Metallurgy – 07 – D

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260/363

C07D 307/93 (2006.01)

Patent

CA 1127654

PRECIS DE LA DIVULGATION: L'invention concerne le mélange racémique de (1R,5S) 6,6-diméthyl 4 (R) [(S)-cyano (3'-phénoxyphényl) méthoxy] 3-oxabicyclo (3.1.0) hexan-2-one et de (1R,5S) 6,6- diméthyl 4(R) [(R)-cyano (3'-phénoxyphényl) méthoxy] 3- oxabicyclo (3.1.0) hexan-2-one. L'invention concerne égale- ment chacun de ces deux énantiomères individuellement. Les produits selon l'invention s'avèrent particulièrement utiles pour l'obtention de l'alcool (S)-cyano 3-phénoxy benzylique qui est lui-même un intermédiaire permettant d'accéder à des esters correspondant ayant des propriétés insecticides.

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