Organic amide-modified polysilazane ceramic precursors

C - Chemistry – Metallurgy – 08 – G

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261/1, 402/29

C08G 77/62 (2006.01) C04B 35/58 (2006.01) C04B 35/589 (2006.01) C04B 35/64 (2006.01)

Patent

CA 2025469

Silazane polymers are prepared by (1) reacting ammonia with one or more halogenated organic silicon compounds con- taining an Si-H bond to produce a silazane ammonolysis prod- uct, (2) mixing the ammonolysis product with 0.1% to 30% by weight of an organic amide or thioamide, and (3) heating to a temperature of 30° to 300°C. Silazane polymers containing alkenyl or alkynyl groups can be cured by supplying energy to generate free radicals. The cured or uncured polymers can be pyrolyzed to produce silicon nitride-containing ceramic materials.

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