Organic di-esters of 2,5 dihydroxy-1,4-dioxanes and process...

C - Chemistry – Metallurgy – 07 – D

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260/354.2

C07D 319/12 (2006.01)

Patent

CA 1057762

ABSTRACT OF THE DISCLOSURE The invention relates to a process for the preparation of 2,5-diacyloxydioxane which comprises reacting 2,5-dichlorodioxane with a salt of formula Me(RCOO)n, in which Me is an alkaline or alkaline-earth metal, R is a lower alkyl radical and n stands for the metal valence. The compounds according to the present invention are useful intermediates for organic syntheses, for instance for the preparation of .alpha.-hydroxy-aldehydes or -ketones, or of .beta.-hydroxy- aminoacids.

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