Organic hybrid planar-nanocrystalline bulk heterojunctions

H - Electricity – 01 – L

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H01L 51/42 (2006.01)

Patent

CA 2670466

A photosensitive optoelectronic device having an improved hybrid planar bulk heterojunction includes a plurality of photoconductive materials (950) disposed between the anode (120) and the cathode (170). The photoconductive materials (950) include a first continuous layer of donor material (152) and a second continuous layer of acceptor material (154). A first network of donor material or materials (953c) extends from the first continuous layer (152) toward the second continuous layer (154), providing continuous pathways for conduction of holes to the first continuous layer (152). A second network of acceptor material or materials (953b) extends from the second continuous layer (154) toward the first continuous layer (152), providing continuous pathways for conduction of electrons to the second continuous layer (154). The first network (953c) and the second network (953b) are interlaced with each other. At least one other photoconductive material (953a, 953d) is interspersed between the interlaced networks. This other photoconductive material or materials (953a, 953d) has an absorption spectra different from the donor and acceptor materials.

La présente invention concerne un dispositif optoélectronique photosensible ayant une hétérojonction de grandeur planaire hybride améliorée comprenant une pluralité de matériaux photoconducteurs disposés entre l'anode et la cathode. Les matériaux photoconducteurs comprennent une première couche en continu d'un matériau de donation et une seconde couche en continu d'un matériau d'acceptation. Un premier réseau de matériau(x) de donation s'étend de la première couche en continu à la seconde couche en continu, fournissant des chemins continus en vue d'une conduction de trous vers la première couche en continu. Un second réseau de matériau(x) d'acceptation s'étend de la seconde couche en continu à la première couche en continu, fournissant des chemins continus en vue d'une conduction d'électrons vers la seconde couche en continu. Le premier réseau et le second réseau sont entrelacés. Au moins un autre matériau photoconducteur est interposé entre les réseaux entrelacés. Ce(s) matériau(x) photoconducteur(s) supplémentaire(s) a (ont) un spectre d'absorption différent de celui des matériaux de donation et d'acceptation.

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