Organic reagents and process of preparing same

C - Chemistry – Metallurgy – 08 – F

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260/1, 402/399,

C08F 112/08 (2006.01) B01J 45/00 (2006.01) C07C 45/68 (2006.01) C07C 205/22 (2006.01) C07D 213/06 (2006.01) C07D 213/16 (2006.01) C07D 215/24 (2006.01) C07D 215/26 (2006.01) C08F 8/24 (2006.01) C08F 8/30 (2006.01) C08F 236/06 (2006.01) C22B 3/26 (2006.01)

Patent

CA 1055034

ABSTRACT A process for producing reagents useful in organic synthesis, for removing metal values, for the capture of aldehydes, of the general formula (I) Image (I) wherein Z designates the (CH2-CH-CH2---) recurring part of a polymeric backbone of a polymer like polystyrene, a copolymer comprising polystyrene and divinylbenzene, butadiene; other copolymers comprising styrene; or wherein Z is the aliphatic moiety of a long-chain aralkyl compound having a terminal aryl group or alkyl, wherein n is an integer, and wherein Q desig- nates a group selected from: a) Image b) Image where R is H, lower alkyl, phenyl, aryl, which may be substituted. c) Image Wherein R is H, lower alkyl, phenyl, aryl, which may be substitu- ted. R" is H, alkyl, aryl, halogen, nitro, carboxyl. Image Wherein R is -H, lower alkyl, aryl, which maybe substituted R1 is H, alkyl or aryl or substituted aryl R2 is H, alkyl or aryl or substituted aryl And wherein Y is -H or a non-interfering substituent, and corresponding compounds with a naphthyl group instead of the Image group. Which comprises chemically binding an activated chemical moiety to a group z Image wherein Z and Y are as defined above accord- ing to the reaction scheme Image wherein O is a functional group as defined under(a), (b), (c) or (d) as defined above, or a functional group which can be converted after the above reaction to such functional group, and X is -C1 or -Br.

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