Organo metallic complexes and the use thereof in epoxidation...

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252/93.D, 260/37

B01J 31/22 (2006.01) B01J 31/16 (2006.01) B01J 31/18 (2006.01) C07D 301/19 (2006.01) C07D 303/04 (2006.01) C08F 8/42 (2006.01)

Patent

CA 1232262

ABSTRACT OF THE DISCLOSURE ORGANOMETALLIC COMPLEXES AND THE USE THEREOF IN EXPOXIDATION OF OLEFINS A family of polymer bound organometallic complexes comprises compounds derived from a metal and a functionalised organic polymer of formula Image wherein X is a polymer backbone bonded to a ligand in which;Y is a group derived from an atom selected from C, Si, N and P; R1, R2, R3 and R4 are, independently, groups selected from H, a C1-C4 alkyl group and a halogen atom; R5 and R6 are, independently, groups selected from H, a C1-C4 alkyl group and a halogen atom, or together with the nitrogen atom form a heterocyclic ring having 5 or 6 atoms; R7 and R8 are, independently, groups selected from H, a C1-C4 alkyl group, an aryl group and a halogen atom and each of n and m have a value from 0 to 10. When the metal is either molybdenum or vanadium the complexes are suitable catalysts for the epoxidation of olefins.

465732

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