Organo-tin compounds, process for their production and use...

C - Chemistry – Metallurgy – 07 – F

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260/436.5

C07F 7/22 (2006.01)

Patent

CA 1121368

Case 3-11129/CGM 1-70/1+2/+ Canada ORGANO-TIN COMPOUNDS, PROCESS FOR THEIR PRODUCTION AND USE THEREOF Abstract of the Disclosure The direct reaction of metallic tin with an .alpha.,.beta.-unsaturated nitrile, hydrogen chloride, hydrogen bromide or hydrogen iodide in the presence of an alcohol yields diorgano-tin dihalides with an iminoester function in the organo groups. This iminoester function can be converted with mercaptans into the corresponding iminothioester function. The novel diorgano-tin dihalides of the formula Image wherein X represents a chlorine, bromine or iodine atom, Y represents an oxygen or sulphur atom, R represents a hydrogen atom and/or alkyl, and R' represents a hydrocarbon group of aliphatic or aromatic character which can contain functional groups, are, for example, valuable intermediates for the production of PVC stabilizers.

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