Organometallic monoacylarylphosphines

C - Chemistry – Metallurgy – 07 – F

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C07F 9/50 (2006.01) A61K 6/00 (2006.01) C07F 9/28 (2006.01) C07F 9/53 (2006.01) C07F 9/58 (2006.01) C07F 9/6521 (2006.01) C07F 9/655 (2006.01) C07F 9/6553 (2006.01) C07J 9/00 (2006.01) C08F 2/50 (2006.01) C08G 77/395 (2006.01) C09D 4/00 (2006.01) C09D 5/44 (2006.01) C09D 5/46 (2006.01) C09D 11/02 (2006.01) C09D 11/10 (2006.01) G03F 7/004 (2006.01) G03F 7/029 (2006.01) G03F 7/075 (2006.01) G03F 7/038 (2006.01)

Patent

CA 2334291

Compounds of the formula I Image in which R1 and R2 independently of one another are C1-C20alkyl, OR11, CF3 or halogen; R3, R4 and R5 independently of one another are hydrogen, C1-C20alkyl, OR11 or halogen; R6, R7, R8, R9 and R10 independently of one another are hydrogen, C1-C20alkyl; C2-C20alkyl which is interrupted once or more than once by nonconsecutive O atoms and which is unsubstituted or substi- tuted by OH and/or SH; or R6, R7, R8, R9 and R10 are OR11, SR11, N(R12)(R13), phenyl or halo- gen; R11 is C1-C20alkyl, C3-C8cycloalkyl, phenyl, benzyl or C2-C20alkyl which is interrupted once or more than once by O or S and which is unsubstituted or substituted by OH and/or SH; R12 and R13 independently of one another are hydrogen, C1-C20alkyl, C3- C8cycloalkyl, phenyl, benzyl or C2-C20alkyl which is interrupted once or more than once by nonconsecutive O atoms and which is unsubstituted or substituted by OH and/or SH; or R12 and R13 together are C3-C5alkylene which can be interrupted by O, S or NR14; R14 is hydrogen, phenyl, C1- C12alkyl or C2-C12alkyl which is interrupted once or more than once by O or S and which is unsubstituted or substituted by OH and/or SH; and M is hydrogen, Li, Na or K; are valuable intermediates for the preparation of unsymmetrical bisacylphosphine oxides and monoa- cylphosphine oxides.

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