Organopolysiloxanes, modified with acrylate groups

C - Chemistry – Metallurgy – 08 – G

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C08G 77/38 (2006.01) C09D 183/06 (2006.01) C09D 183/07 (2006.01)

Patent

CA 2131930

Organopolysiloxanes, which terminally, laterally or both have at least one group of the formula (see formula I) as well as at least one acrylate group, linked over a bridge element to this group, is obtained by hydrosilylation of organopolysiloxanes with at least one SiH group by compounds, which have at least two acrylate groups, in equimolar amounts at a temperature of 60° to 130°C in presence of rhodium catalysts. The rhodium catalysts cause a 1,2 addition to take place during the addition reaction between polyacrylates and hydrogen siloxanes.

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