Oxidation catalyst and preparation of epoxides from olefins,...

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B01J 29/89 (2006.01) B01J 29/04 (2006.01) C07D 301/04 (2006.01) C07D 301/08 (2006.01) C07D 303/04 (2006.01)

Patent

CA 2256383

An oxidation catalyst based on titanium or vanadium silicalites with a zeolithic structure and containing 0.01 to 30 wt.% of one or more noble metals from the group ruthenium, rhodium, palladium, osmium, iridium, platinum, rhenium, gold and silver, in which the oxidation catalyst is formed by solidifying shaping processes. Said oxidation catalyst is used in the production of epoxides, especially propylene oxide, from olefines, hydrogen and oxygen.

L'invention concerne un catalyseur d'oxydation à base de silicalites de titane ou de vanadium à structure zéolithique et contenant entre 0,01 et 30 % en poids d'un ou de plusieurs métaux nobles appartenant au groupe comprenant le ruthénium, le rhodium, le palladium, l'osmium, l'iridium, le platine, le rhénium, l'or et l'argent. Ce catalyseur d'oxydation se caractérise en ce qu'il est obtenu par des procédés de façonnage solidifiant. Ce catalyseur d'oxydation s'utilise pour produire des époxydes, notamment de l'oxyde de propylène, à partir d'oléfines, d'hydrogène et d'oxygène.

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