Oxidation of ketones

Details Oxidation of ketones Oxidation of ketones

C - Chemistry, Metallurgy

07

D

C07D 313/18 (2006.01) C07C 67/42 (2006.01) C07C 407/00 (2006.01) C07C 409/24 (2006.01) C07C 409/26 (2006.01) C07D 307/33 (2006.01) C07D 309/30 (2006.01) C07D 313/04 (2006.01) C07D 315/00 (2006.01)

Patent

CA 2157385

A process for the catalysed oxidation of ketones to esters or lactones with hydrogen peroxide in the presence of a carboxylic acid or anhydride solvent is provided. The process employs gamma alumina as a heterogeneous catalyst. In certain preferred embodiments, the catalyst also contains a tungsten-containing heteropolyacid. Preferably, the heteropolyacid contains phosphorus. In a related process, the catalyst accelerates the formation of percarboxylic acid solutions.

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