Oxidation of organic compounds using a catalyzed cerium(iv)...

Details Oxidation of organic compounds using a catalyzed cerium(iv)... Oxidation of organic compounds using a catalyzed cerium(iv)...

C - Chemistry, Metallurgy

07

C

260/396, 204/55

C07C 50/12 (2006.01) B01J 27/053 (2006.01) B01J 27/25 (2006.01) B01J 31/02 (2006.01) B01J 31/04 (2006.01) C07C 46/04 (2006.01) C07C 50/10 (2006.01) C25B 3/02 (2006.01) C07B 61/00 (2006.01)

Patent

CA 1271485

ABSTRACT OXIDATION OF ORGANIC COMPOUNDS USING A CATALYZED CERIUM(IV) COMPOSITION A process for oxidizing aromatic and alkyl substituted aromatic compounds to quinonoid compounds by contacting an aromatic and alkyl aromatic compound with an acidic, aqueous solution of ceric oxidant in the presence of a catalytic amount of chromium cations. The present process provides a means of forming the desired quinonoid product in good yields and high selectivity.

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