Oxidation of organic compounds using thallium ions

Details Oxidation of organic compounds using thallium ions Oxidation of organic compounds using thallium ions

C - Chemistry, Metallurgy

07

C

204/55, 260/577.

C07C 49/784 (2006.01) C07C 45/28 (2006.01) C07C 205/47 (2006.01) C25B 1/00 (2006.01) C25B 3/02 (2006.01)

Patent

CA 1271490

ABSTRACT OXIDATION OF ORGANIC COMPOUNDS USING THALLIUM IONS Aqueous acidic solutions of certain thallium(III) organosulfonate having at least 0.1 molar thallium ion concentration are contacted with an organic compound to form a related oxidized organic compound. The oxidized compound is separated and recovered from the solution and the resultant thallium(I) rich solution is electrochemically treated to regenerate thallium(III) which, in turn, can be reused in a cyclical process. The present invention provides a highly effective means of oxidizing organic substrates.

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