Oxidation process using microchannel technology and novel...

B - Operations – Transporting – 01 – J

Patent

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B01J 19/00 (2006.01) B01J 23/58 (2006.01) B01J 23/63 (2006.01) B01J 23/89 (2006.01) C01B 3/38 (2006.01)

Patent

CA 2525256

A process is disclosed for converting a hydrocarbon reactant to CO and H2. The process comprises: (A) flowing a reactant composition comprising the hydrocarbon reactant (116) and oxygen or a source of oxygen (118) through a microchannel reactor (100) in contact with a catalyst under reaction conditions to form the product. The product formed in step (A) may be converted to a product comprising CO2 and H2O in a microchannel reactor. A catalyst is disclosed which comprises a composition represented by the formula M'a M2b M3C AId OX wherein: M1 is Rh, Ni, Pd, Pt, Ru, Co or a mixture of two or more thereof; M2 is Ce, Pr, Tb or a mixture of two or more thereof.

Procédé permettant de convertir un réactif hydrocarbure en CO et H¿2?, qui consiste (A) à faire couler une composition réactive contenant le réactif hydrocarbure et de l'oxygène ou une source d'oxygène à travers un réacteur à microcanaux en contact avec un catalyseur dans des conditions de réaction pour former le produit. Le produit formé à l'étape (A) peut être converti en un produit contenant CO¿2? et H¿2?O dans un réacteur à microcanaux. La présente invention concerne également un catalyseur qui contient une composition représentée par la formule M?1¿¿a? M?2¿¿b? M?3¿¿c? Al¿d? O¿x? dans laquelle M?1¿ représente Rh, Ni, Pd, Pt, Ru, Co ou un mélange de deux de ces substances ou plus, et M?2¿ représente Ce, Pr, Tb ou un mélange de deux de ces substances ou plus.

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